Wear safety glasses at all times. Voluntary Risk assessment of COPPER, COPPER II SULPHATE PENTAHYDRATE, COPPER(I)OXIDE, COPPER(II)OXIDE, DICOPPER CHLORIDE TRIHYDROXIDE. immediately or shortly after exposure to Copper Chloride: * Contact can severely irritate and burn the skin and eyes with possible eye damage. Solid* only: very toxic to aquatic life. Expert Group on Vitamins and Minerals. Since no endpoints of concern have been identified, EPA has not conducted a quantitative risk assessment for copper sulfate pentahydrate. COPPER SULPHATE Long-term exposure limit (8-hour TWA): WEL 1 mg/m3 Short-term exposure limit (15-minute): WEL 2 mg/m3 WEL = Workplace Exposure Limit 8.2. Death may occur from shock or renal failure. Three copper-based algaecide products were investigated for use in a drinking water source to address cyanobacteria growth. All practical worksheets must be risk assessed by the centre before use. The optimal dose of Cutrine Ultra was determined to be a quarter dose (corresponding to 0.125 mg/L … Conclusion regarding the peer review of the pesticide risk assessment of the active substance Copper (I), copper (II) variants namely copper hydroxide, copper oxychloride, tribasic copper sulfate, copper (I) oxide, Bordeaux mixture. H319 Causes serious eye irritation. Volumetric flask, 100 cm3 5. Part 1 - Investigation using inert electrodes Small-scale method for determining the mass loss when heating a hydrated salt to constant mass (of anhydrous salt). The only evidence of human cancer related to inhala- tion exposure to copper was the suggestion by Plmental and Menezes (1975) that persons exposed to copper sulfate mist In Bordeaux mixture (vineyard sprayer's disease) may be at additional risk for the development of pul- … * Breathing Copper Chloride can irritate the nose, throat and lungs causing coughing and wheezing. ammonium carbonate, copper-ammonia complex, copper oxychloride sulfate, copper sulfate anhydrous, and copper ethanolamine). Too much exposure to copper may occur from drinking contaminated water, eating foods that contain pesticide residues, or swimming in waters where copper sulfate was recently applied. Risk Assessment Report Zinc sulfate (Food Additives) Food Safety Commission of Japan (FSCJ) September 2015 ABSTRACT FSCJ conducted a risk assessment of zinc sulfate (CAS No. The conclusions of the EFSA following the peer review of the initial risk assessments carried out by the competent authorities of the rapporteur Member State, France, and co-rapporteur Member State, Germany, for the pesticide active substance copper compounds are reported. Unfortunately, the long-term side-effects outweigh the short-lived benefits. Food Standards Agency, UK. … They are very toxic to fish and aquatic invertebrates, such as crab, shrimp and oysters. • Risk assessment and risk management are the responsibility of the centre. You may be potentially affected by this action if you are an agricultural producer, food manufacturer, or pesticide manufacturer. Copper sulfate presents a health risk because the compound breaks down into copper. Inform or check with students what the precipitate is for each reaction. Core practical Making copper sulfate crystals. Copper sulfate has historically provided a quick fix for algae problems in lakes and ponds. 7758-99-8 6.93% Copper (II) Sulfate, Pentahydrate (7758 -99 -8) RQ (Reportable quantity, section 304 of EPA's List of Lists) 10 lb 15.2. International regulations CANADA Copper (II) Sulfate, Pentahydrate (7758 -99 -8) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations The use of copper sulfate for temporary algae control can produce significant zooplankton mortality, and may also adversely • Ecological assessment- Data gaps were not identified for AFCs for the risk assessment. Hazards, risks and precautions. Notes to assessor and technician The practical activities suggested for this assignment are This page provides a framework for displaying NCEA EIMS records. Regulatory scrutiny and perceived non-target species impacts supported the need for an accurate risk assessment of fate and effects of copper applied as a pesticide. Indication of any immediate medical attention and special treatment needed . Quantitative analysis when using copper electrodes will be expected. The remainder of this section describes our findings for the general population, subpopulations at special risk, and occupationally-exposed populations. Copper (II) Sulfate - Toxicity Data: Oral TDLO (human): 272 mg/kg; Intraperitoneal LD50 (rat): 18700 ug/kg; Oral LD50 (rat): 300 mg/kg; Oral LD50 (mouse): 43 mg/kg; Intraperitoneal LD50 (mouse): 20 mg/kg; Information on Toxicological Effects: Copper (II) Sulfate - Investigated as an agricultural chemical, mutagen, and tumorigen. ed during the course of the experiment using copper sulfate, as an example. Copper sulfate and other chelated or complex copper forms are commonly used to manage nuisance and noxious algae and invasive weeds through direct application to aquatic systems. 7758-98-7 Revision Date 2007 -03 -01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components Copper sulphate CAS-No. Precautionary Statements P273 Avoid release to the environment. Potential Health Effects . citri by franklin behlau a dissertation presented to the graduate school of the university of florida in partial fulfillment of the requirements for the degree of doctor of philosophy university of florida 2010 page 2 2 2010 franklin behlau page 3 7758-98-7 Revision Date 2007-03-01 (texto en ingles) by "Acta Scientiarum. No additional information available . Some people may exhibit a sensitivity to copper if copper sulfate makes contact with their skin. Carcinogen Risk Assessment also utilize those Guidelines where indicated (Federal Register 61(79):17960-18011, April 23, 1996). H319 Causes serious eye irritation. Risk assessment Copper(II) sulfate pentahydrate Signal word: Caution Hazard statements H302 Harmful if swallowed. Copper (II) Sulfate, Pentahydrate CAS-No. The contractor applied two algaecide treatments of copper sulfate to the lake, which resulted in killing around 10,000 fish. The following topics are addressed: Technical Name Cupric sulfate Hazard Class 9 Packing Group III TDG UN-No UN3077 Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Based This is an outline of the required steps to undertake one of these methods. The High Purity Copper Sulfate Solution market outlook looks extremely promising is a valuable source of insightful data for business strategists. Show more. in the form of copper sulfate in its use as a fungicide and algicide. Also, used to test protein in Biuret test. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. risk assessment of cadmium metal and cadmium oxide CSTEE (28 May 2004) advised against using the added risk approach. Copper(II) sulfate sc-211133 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Copper(II) sulfate STATEMENT OF HAZARDOUS NATURE ... RISK Harmful if swallowed. Risk assessment Copper sulfate solution- risks are causes skin irritation, serious eye damage and harmful if swallowed. Copper is an essential trace element that is included in some over-the-counter multivitamin and mineral supplements, even though copper deficiency is quite rare and supplementation is rarely needed. 2003. There are a number of ways that you could make copper sulfate crystals in Chemistry. Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates • 1.0M dilute sulfuric acid (IRRITANT) is covered by Hazcard 98A • copper(II) oxide (HARMFUL) is covered by Hazcard 26 • copper(II) sulfate (HARMFUL) is covered by Hazcard 27C Small filter funnel and filter paper, to fit volumetric flask 6. 4.3. . Measuring cyli… Free Online Library: Copper sulfate acute ecotoxicity and environmental risk for tropical fish/Ecotoxicidade aguda e risco ambiental do sultado de cobre para peixes tropicais. This draft screening assessment focuses on the copper moiety and therefore considers copper in its elemental form, copper-containing substances, and copper released in dissolved, solid, or particulate form. ... Chlorinated Dioxins And Furans From Kelp And Copper Sulfate: Initial Investigations Of Dioxin Formation In Mineral Feed Supplements (Journal Article)., 63:183-186, (2003). * Nickel Sulfate may damage the testes and cause infertility in males. resulting from copper, acute and chronic dietary endpoints were not selected. Copper(II) Sulfate Pentahydrate is a moderately water and acid soluble Sodium source for uses compatible with sulfates. It has also been reported that copper H315 Causes skin irritation. Splattering of copper sulfate solution. The EPA risk assessment for birds and small mammals (based on dietary consumption) indicates that some risk may be present to birds or mammals at the worst-case scenario. While attempting to make ponds more aesthetically pleasing, the balance of the ecosystem is skewed, pond filling accelerates, and the possibility of algae toxicity increases. Each group will need: ... Why is a water bath used to evaporate the water from the copper sulfate solution instead of heating the … of copper sulfate solution in GCSE Chemistry. Copper sulfate is not a known carcinogen. Beaker, 250 cm3 3. RISK ASSESSMENT Risk Injury Prevention Harmful if swallowed Copper sulfate is an irritant If swallowed, give water and call a physician. The amounts of copper found in typical supplements has not been associated with serum enzyme elevations or with clinically apparent liver injury. H315 Causes skin irritation. This risk assessment is provided as an example only, and you must perform your own risk assessment before doing this experiment. convulsions, paralysis, and coma. Share. 1 mol dm-3 zinc sulfate solution [ZINC SULFATE IS AN IRRITANT] strip of filter paper soaked in saturated potassium nitrate solution [SOLID POTASSIUM NITRATE IS AN OXIDANT] Health and safety A risk assessment must have been carried out. Fully risk assessment and industry recommendations were made for Copper Sulfate (Cas 7758-98-7) in a special period. Copper uptake, essentiality, toxicity, detoxification and risk assessment in soil-plant environment. Water added to anhydrous solid copper(II) sulfate(VI) produces heat. Doing so will cause serious diarrhea and vomiting. Biological Sciences (UEM)"; Science and technology, general Biological indicators Environmental aspects Compuestos de cobre Contaminacion Productos Toxicologia Contaminacion … E X T O X N E T. Extension Toxicology Network - Pesticide Information Profiles. Copper Final Work Plan & Data Call -In . SAFETY DATA SHEET COPPER SULPHATE 0.01M According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name COPPER SULPHATE 0.01M 1.2. Common Name: NICKEL SULFATE CAS Number: 7786-81-4 DOT Number: NA 9141 ----- HAZARD SUMMARY * Nickel Sulfate can affect you when breathed in and may be absorbed through the skin. 7. In case of contact with eyes or skin, flush with water For eyes, eye wash 20 minutes then seek medical attention 7. As copper(II)sulphate pentahydrate is the commercially dominant form of copper (II)sulphate, while the anhydrate has little commercial use, it has been specifically decided to include copper(II)sulphate pentahydrate in the survey. Eye protection (goggles) 2. 7758-98-7 Revision Date 2007 -03 -01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components Copper sulphate CAS-No. This screening assessment therefore considers copper-containing substances beyond those identified as priorities for assessment. 8. For antimicrobial uses, the Agency determined: • Human health assessment- Exposure database is complete, no additional data needed. Copper sulfate is very toxic to organisms that eat fish, and highly toxic to fish, amphibians, and crustaceans. In the case of copper hydroxide, basic copper sulfate, and copper sulfate pentahydrate, available acute toxicity studies indicate the potential for products containing these coppers to cause severe irritation to workers or handlers via skin, eye, or inhalation exposure routes. Eye irritation Wear safety goggles. COPPER SULFATE (COPPER SULFATE) Chemwatch: 11428 Version No: 7.1.1.1 Safety Data Sheet according to WHS and ADG requirements Issue Date: 01/01/2013 Print Date: 01/04/2017 L.GHS.AUS.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name COPPER SULFATE (COPPER SULFATE) Consider the Hess’s Law cycle below ΔH3 anhydrous copper(II) sulfate + (aq) hydrated copper(II) sulfate ΔH1 ΔH2 copper(II) sulfate … screening-level ecological assessment indicated that copper can pose acute risks to various organisms, with the greatest risk to aquatic organisms resulting from direct water applications and runoff from fields adjacent to water bodies. In analytical chemistry, it is used in Fehling′s solution and Benedict′s solution to test for reducing sugars. The safety measure to avoid this is to wear goggles and avoid skin contact with the solution. 1.0M sulfate, ≥ 1.3 M nitrate): skin irritant; cause serious eye damage; harmful if swallowed (especially saturated solutions for crystal-growing). TERA is a founding member of the Alliance for Risk Assessment, a collaborative effort of organizations dedicated to supporting public health protection by improving the process, research, and efficiency of risk assessment. Copper sulfate is a severe eye irritant and can cause substantial damage to the eyes. In humans, ingestion of gram quantities of copper salts may cause gastrointestinal, hepatic, and renal effects with symptoms such as severe abdominal pain, vomiting, diarrhea, hemolysis, hepatic necrosis, hematuria, proteinuria, hypotension, tachycardia, convulsions, coma, and death (U.S. AF, 1990). The enzyme will be deactivated and the reac-tion comes to a standstill. The second part of this investigation covers the products formed during the electrolysis of copper sulfate solution using inert (graphite) electrodes. Hazard Class 9 Packing Group III IATA UN-No UN3077 Proper Shipping Name Environmentally hazardous … In 1985, EPA proposed a sulfate health advisory (HA) of … Place a microscope slide over the water bath. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. Copper(II) sulfate sc-211133 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Copper(II) sulfate STATEMENT OF HAZARDOUS NATURE ... RISK Harmful if swallowed. It can kill bacteria, algae, roots, plants, snails, and fungi. Risk assessment guidance for hydrated and anhydrous copper sulfate. Risk Assessment Report (12/16) 16./17.11.2017 European Conference on Copper in Plant Protection ERA of Copper Compounds in the EU Active Substance Evaluation: State of Play (Frische/König, UBA) Plastic weighing dish (boat) 9. Copper is an essential mineral. Department of Environmental Protection issued a fine stating that copper sulfate applications should be spaced 7 to 14 days apart whereas the company made two applications spaced only 3 days apart. Thus, a quantitative toxicity assessment was not conducted for dietary, dermal, oral or inhalation exposures. Copper, as a salt, is toxic and has the potential to harm multiple organs. 7758-98-7 Revision Date 2007-03-01 Pennsylvania Right To Know Components Copper sulphate CAS-No. 1, using the highest used to control bacteria and fungus growth on fruits, vegetables, and other crops Significant shifts (p < 0.05) in D. magna 48-h median lethal concentration (LC50) values were found when algae were present in exposures along with a copper salt or a chelated copper formulation. The following list of North American Industrial Classification System (NAICS) codes is not intended to be exhaustive, but rather provides a guide to help readers determine whether t… Enlargement/affection of the liver. Aggregate Risk Aggregate risk refers to the combined risk from dietary (food and drinking water) and residential or other non-occupational exposures. Assume that all of the reagents and liquids are toxic, corrosive and flammable. We present a case of chronic copper sulfate poisoning in a 66-year-old man with dysphagia to solids and liquids, anaemia, acute kidney injury, liver cytolysis and hypocalcaemia. A bioequivalence study was performed to compare the five variants of copper, copper hydroxide, copper oxychloride, Bordeaux mixture, tribasic copper sulfate and copper (I) oxide with copper sulfate pentahydrate on bile-cannulated rats demonstrating that toxicological studies on copper sulfate could be used in the toxicological risk assessment of the five variants. ammonium carbonate, copper-ammonia complex, copper oxychloride sulfate, copper sulfate anhydrous, and copper ethanolamine). Apparatus. Copper is also a component of the diet of infants and children and also an essential element of their diet. When handling copper sulfate boots, gloves, and goggles should be worn at all times to minimize the risk for exposure or ingestion. Copper sulfate pentahydrate crystals, powder, or liquid are the most convenient ways to handle copper sulfate when cleaning gardens, pools, or drains. Author links open overlay panel Zunaira Shabbir a Aneeza Sardar a Abrar Shabbir a Ghulam Abbas a Saliha Shamshad a Sana Khalid a Natasha a Ghulam Murtaza b Camille Dumat c d e Muhammad Shahid a. RISK ASSESSMENT Risk Injury Prevention Harmful if swallowed Copper sulfate is an irritant If swallowed, give water and call a physician. Copper sulphate CAS-No. "The screening-level ecological assessment indicated that copper can pose acute risks to various organisms, with the greatest risk to aquatic organisms * Nickel Sulfate is a CARCINOGEN--HANDLE WITH EXTREME CAUTION. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. Copper sulfate is an inorganic compound that combines sulfur with copper. The method, which uses a mini spirit burner and an alternative crucible, reduces the.. more. Copper sulphate CAS-No. • Safety goggles should be worn throughout. The “Feed Grade Copper Sulfate... Apr 16, 2021 (The Expresswire) -- "Final Report will add the analysis of the impact of COVID-19 on this industry." COPPER SULPHATE PENTAHYDRATE Signal Word Warning Hazard Statements H302 Harmful if swallowed. . EINECS No: 231–159–6, 231–847–6, 215-270-7, 215–269–1, 215-572-9. Exposure to Copper Sulfate . Beaker, 100 cm3 4. ... 27.4.1 Risk Assessment on COVID-19. Method filter paper soaked in V zinc copper 1 mol dm-3 zinc sulfate 1 mol dm-3 copper sulfate Copper(II)sulfate is used in electroplating and in mining industries. 1 risk assessment of copper and streptomycin resistance development in xanthomonas citri subsp. Basin was found to have levels of copper exceeding the 3.1 mg/L limit permitted under The Clean Water Act (CWA). H410 Very toxic to aquatic life with long lasting effects. The rest of the questions, focus on both how to make a soluble salt and the underlying chemistry. Responsible for this voluntary risk assessment. their own safety risk assessment before carrying out this experiment. To understand any potential for health risks to consumers from the use of ACQ- treated wood, an extensive hazard evaluation and risk assessment was undertaken and is reported herein. Reboil the water, and make a two layer bottle top hot water bath. Exposure assessment, dose-response assessment, and risk characterization were conducted for those effects for which the evidence was judged to be either strong or modest. It is important in this practical activity to use appropriate apparatus … Eye irritation Wear safety goggles. In 1979, EPA established a secondary maximum contaminant level (SMCL), a non-enforceable guidance level for aesthetic quality, at 250 mg/L for sulfate in drinking water. Allow unreacted copper oxide to settle to the bottom of the cap. Exposure controls Appropriate engineering controls Provide adequate ventilation. Copper sulfate. Copper(II) sulfate pentahydrate powder EMPROVE® ESSENTIAL Ph Eur,BP,USP; CAS Number: 7758-99-8; Synonyms: Copper monosulfate pentahydrate, Copper vitriol pentahydrate,Copper(II) sulfate pentahydrate; find SAFC-102788 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich Copper intoxication causes intravascular haemolysis followed by liver and kidney failure that can be fatal. 1. copper sulfate, mercury(II) nitrate, potassium chromate, potassium fluoride, potassium iodide, sodium chloride, sodium hydroxide, sodium sulfide, silver nitrate, Teacher: Give directions in the handling & disposal of chemicals according to your risk assessment. Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson's disease. * Copper Chloride can irritate the stomach causing salivation, nausea, vomiting, stomach pain and diarrhea. Bench-scale experiments were used to determine the optimal dose of each product given Lake Rockwell’s indigenous population and reservoir-specific characteristics. Splattering of copper sulfate solution. It can kill bacteria, algae, roots, plants, snails, and fungi. Nevertheless, the environmental risk evaluation has highlighted a maximum acceptable dose not to exceed of 430 ppm of copper sulfate pentahydrate and the human risk evaluation has highlighted a maximum acceptable dose not to exceed of 6272 ppm of copper sulfate pentahydrate for healthy people and of 314 ppm for enfeebled people. SCHER remains of the opinion that the added approach can only be used if a region-specific ‘realistic’ natural background can be established and if this is then used to Measuring cylinder, 50 cm3 10. As a practical solution, the choice was made to include all relevant copper(II)sulphate compounds in the study. Irritating to eyes, respiratory system and skin. Students: 1. What is copper sulfate? Copper Ecological Risk Human Health Risk Socioeconomic Risk What’s at risk? Irritating to eyes, respiratory system and skin. CAS No: 7440-50-8, 7758-98-7, 1317-3-1, 1317–38–0, 1332-65-6. Crops and agriculture are cleaned after being treated with copper sulfate and there’s minimal risk to ingesting it from a treated crop as it primarily binds itself to soil sediments. It is possible to be exposed to copper sulfate if you use it for farming or gardening purposes. The EFSA 2013 risk assessment on acetic acid found many data gaps and the need for further information, ... Copper sulfate and similar fungicides have been poisonous to sheep and chickens on farms at normal application rates. Test tube rack 8. either as copper sulfate, or as a copper chelate. If inhaled, the dust can cause respiratory irritation. Tilt the ‘reaction bottle cap’ and pipette off the blue copper sulfate solution; Pipette 10 drops of the copper sulfate solution onto the slide over the waterbath. 7758-98-7 Revision Date 2007-03-01 Test tubes, x6 (must have a capacity of at least 10 cm3) 7. 7758-98-7 Revision Date 2007-03-01 Pennsylvania Right To Know Components Copper sulphate CAS-No. Copper 34 270 68.1 3.1 9 1300 N/A Zinc 150 410 158 81 120 N/A N/A Notes: ... factors for risk Cu, Zn, pH, sulfides/sulfate, DO, hardness, salinity, TSS Bank Potential source of metals, pH ... factors for SSTLs in the risk assessment, and may indicate lower accumulation factors that This involves setting up an electrolysis to investigate the effect of changing the current on the mass of the copper electrodes used in the electrolysis of copper sulfate solution. an inorganic compound that combines sulfur with copper. It is used as a dehydrating agent for forming and manipulating acetal groups. Copper(II) sulfate Revision Date 23-Jan-2018 Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Alkaline copper quaternary (ACQ) Type D is one of several pesticide replacements for CCA as a wood preservative. Part 4 - Determining the concentration of copper(II) sulfate solution by colorimetry Practical worksheets can be substituted or adapted according to resourcing and local requirements. Presented at Hydrogen Sulfide Health Research and Risk Assessment Symposium, Research Triangle Park, NC, October 31-Nov. 2, 2000. risk assessment worksheet is also included in the additional resources and could be used as a follow-up activity or in preparation for students preparing another soluble salt. The Canadian Environmental Protection Act, 1999 (CEPA) (Government of Canada, 1999) provides the authority for the Minister of the Environment and the Minister of Health (the ministers) to conduct assessments to determine if Risk Assessment - Copper. RISK ASSESSMENT Risk Injury Prevention Harmful if swallowed Copper sulfate is an irritant If swallowed, give water and call a physician. . Splattering of copper sulfate solution. Eye irritation Wear safety goggles. In case of contact with eyes or skin, flush with water For eyes, eye wash 20 minutes then seek medical attention 7. 1996. Copper sulfate should not be ingested. Subject and Scenario Dose of Concern Reference Value Rating risk assessment was not conducted. In case of contact with eyes or skin, flush with water For eyes, eye wash 20 minutes then seek medical attention 7. It provides the industry overview with growth analysis and historical & futuristic cost, revenue, demand and supply data (as applicable). natural / copper sulfate, pentahydrate / copper sulphate, pentahydrate / copper vitriol / ... Risk of pneumonia. The research analysts provide an elaborate description of the value chain and its distributor analysis. The report also compares … Risk could be modeled with MAMPEC. It can be found in the environment, foods, and water. The context of the peer review was that required by Commission Implementing Regulation (EU) No 844/2012. The toxicity of copper sulfate depends on the copper content.
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