GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. 1 (H318) Skin Irrit. Description of first aid measures General advice : Consult a physician. Titanium dioxide does not have a harmonised classification and is not listed in Annex VI of CLP. Name Product identifier % GHS-US classification Titanium dioxide (CAS No) 13463-67-7 <1.078 Carc. The Titanium dioxide case shows as an example the effects a classification as a potential carcinogen under EU´s CLP-regulation can have in a globalised world. Composition / Information On Ingredients HAZARDOUS SUBSTANCES Chemical Name CAS-No. Not applicable to this product. Not applicable . 2A, H319 Full text of hazard classes and H-statements : see section 16 3.2. Melting Point: 1,843 °C (3,349 °F; 2,116 K) Boiling Point: 2,972 °C (5,382 °F; 3,245 K) Density: 4.23 g/cm3 (rutile)，3.78 g/cm3 (anatase) Solubility in water: Insoluble. 4 (Inhalation), H332 If welding must be performed in damp locations or with wet clothing, on metal structures or when in cramped positions such as ... Titanium dioxide 13463-67-7 <10% Sodium silicate 1344-09-8 <10% Manganese 7439-96-5 <10% Iron oxide 1309-37-1 <10% Nickel 7440-02-0 <1% Name Product identifier % GHS-US classification Titanium dioxide (CAS-No.) SECTION 1: Identification. EC Number 0013463-67-7 Titanium dioxide 93-100 Not Available 236-675-5 See … Name Product identifier % GHS-US classification Tridymite (CAS-No.) If you feel unwell, seek medical New Window. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE ... scope of WHMIS 2015 and Globally Harmonization System (GHS). (Reference 2 - Test Data) showed no significant carcinogenicity. Mutagenicity: Not known to … 2, H351 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Titanium Dioxide Pigment Date: 01.04.15 Version: 6.0 Replaces version: 5.0 Page 1 of 13 1. On Feb. 18, the European Commission published a regulation classifying titanium dioxide (TiO 2) containing greater than 1% respirable dust content by inhalation as a Category 2 [Animal] Carcinogen. Titanium Powder . Chemical Name Weight% Classification H Statements 0013463-67-7 Titanium dioxide 93-100 Not classified CAS-No. Titanium(IV) oxide Revision Date 17-Nov-2020 Harmonized System of Classification and Labeling of Chemicals (GHS). % GHS Classification Carcinogen Calcium carbonate 471-34-1 38 - 42 Eye Dam. Although some manufacturers of pigment grade TiO 2 also purposely produce nano-TiO 2 , the vast majority of TiO 2 made and sold is pigmentary grade. Pure titanium dioxide is a fine, white powder that provides a bright, white pigment. The proposal has been changed slightly, so now a classification of Cat 2 carcinogen, H351, Suspected of causing cancer through inhalation, would apply to titanium dioxide as a substance and in mixtures containing 1% or more: a) titanium dioxide particles < 10 micrometer and Little Pro on 2016-01-06 Views: . Titanium dioxide has been char-acterized by IARC as possibly carcinogenic to humans (Group 2B) through inhalation (not ingestion). GHS label elements ... Titanium dioxide 13463-67-7 OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) No need for classification according to GHS criteria for this product. This product does not contain any hazardous chemical that … This proposed Harmonised Classification sits within the draft 14th ATP to CLP (at least the 14th ATP should be published in number order, unlike the “13th ATP then 12th ATP” situation). inks, varnishes and printing inks) also seems to be off the table. Name Product identifier % GHS-US classification TITANIUM DIOXIDE (CAS-No.) We provide Titanium Dioxide safety data sheets view and download at Echemi.com. result in GHS classification: Electrical Shock can kill. Not applicable . Titanium dioxide Oral LD50: Rat > 10,000 mg/kg Dermal LD50: rabbit > 5,000 mg/kg GHS LC50 (vapour): Acute toxicity point estimate 55 mg/l Methacrylic acid Oral LD50: Rat 1,060 mg/kg Dermal LD50: Rabbit 500 - 1,000 mg/kg Inhalation LC50: Rat 7.1 mg/l /4 h Amine curative N.D. Germ cell mutagenicity: No classification proposed This action follows the fall decision by CARACAL— the expert group that advises the European Commission and European Chemicals Agency (ECHA) on questions related to REACH and … CLASSIFICATION & LABELLING; Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. An additional technical issue impacting the classification proposal is that the animal studies on titanium dioxide carcinogenicity being emphasized were done solely with exposure to nanoparticles. Titanium Dioxide can affect you when inhaled. Titanium dioxide (nanoparticle) Substance ID : H28-B-019, C-027B : Classification year (FY) FY2016 : Ministry who conducted the classification : Ministry of Health, Labour and Welfare (MHLW)/Ministry of the Environment (MOE) New/Revised : Revised : Classification result in other fiscal year : FY2009 FY2006 Download of Excel format : Excel file The International Agency for Research on Cancer (IARC) considers titanium dioxide a Group 2B carcinogen, i.e. ... DuPont scientists conclude that titanium dioxide will not cause lung cancer or chronic respiratory diseases in humans at concentrations experienced in the workplace. In the US, Canada, and most other jurisdictions, titanium dioxide is classified in Carcinogenicity – Category 2 under GHS. Background: Globally Harmonized System (GHS) The GHS. Titanium Dioxide (White/Gray) 13463-67-7 236-675-5 0338 0 – 15% HAZARD CLASSIFICATION: [Xi] Irritant RISK PHRASES: R36/38 Carbon Black (Black/Gray) 1333-86-4 215-609-9 0471 1 – 10% Not a hazardous substance according to the GHS system of classification/Labelling of Chemicals (GHS). Google Patents:Titanium hydroxide, photocatalyst obtainable from the same and coating agent comprising the same PubMed:Evaluating the effectiveness of marine actinobacterial extract and its mediated titanium dioxide nanoparticles in the degradation of azo dyes. HS Code Of 28230010, Titanium Dioxide , Indian HS Classification 28230010, Harmonised Code 28230010, Duty Structure Titanium Dioxide Reg Adams: The paint industry consumed nearly 3.5 million tonnes of TiO 2 in 2019, accounting for 55% of total world consumption. Classification of the substance or mixture Classification (GHS-US) Acute Tox. The CLP amendment will be … Chemicals (GHS). Individual Protection Measures, Such as Personal Protective Equipment 5.2. Appearance: White solid. 97 (1979)). All over the world there are different laws on how to identify the hazardous properties of chemicals (called 'classification') and how information about these hazards is then passed to users (through labels and safety data sheets for workers). The hazard pictograms and statements are used to signal the dangers in substances and for the safety of workers. Titanium dioxide is listed by the IARC under its 2B classification. GHS classification of mixture is complex mainly because it is impossible to test every mixture to obtain the data needed for classification. Classified according to the criteria of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), The United States Occupational Safety and Health Administration’s Hazard Communication Standard (29 ... Titanium dioxide 13463-67-7 1 - <5% Limestone 1317-65-3 1 - <5% Manganese 7439-96-5 1 - <5% Iron oxide 1309-37-1 0.1 - <1% Two new supplemental label elements (EUH211 and EUH212) have been added for products with TiO2. The label on the packaging of liquid mixtures containing 1 % or more of titanium dioxide particles with aerodynamic diameter equal to or below 10 μm shall bear the following statement: Contact: Heidi McAuliffe, hmcauliffe@paint.org. Comments: This mixture does not meet the criteria for classification according to OSHA Hazard Communication Standard 2012 (HCS 2012) 1900.1200. Use approved Class D Titanium dioxide (TiO 2) is a white solid inorganic substance that is thermally stable, non-flammable, poorly soluble, and not classified as hazardous according to the United Nations’ (UN) Globally Harmonized System of Classification and Labeling of Chemicals (GHS). ATP 14 also contains Acute Toxicity Estimates (ATE) that must be used for the classification of 10 chemicals. 2 2.2 GHS label elements, including … 2 (Inhalation:dust,mist) H330 Skin Corr. Cat 1 (H317) Aquatic Acute Cat 1 (H400) Aquatic Chronic Cat 1 (H410) * Carcinogen classification applies to respirable forms only. 3. FIRST AID MEASURES 4.1 Description of first aid measures General advice Consult a physician. Liq. This will become effective in October of 2021. Titanium dioxide. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 GHS06 GHS07 Signal word (GHS-US) : Danger and According to EC-Regulation 2015/830 4/8 UNIPAK jointing compound DNEL (Titanium dioxide): 10 mg/m3 Exposure: Inhalation Duration of Exposure: Long term NOTES; The CAS numbers for different forms are: CAS 13463-67-7 (anatase/rutile); CAS 1317-70-7 (anatase); CAS 1317-80-2 (rutile). The European Parliament and the Council of Ministers now have two months to object. Call physician, poison control center or Titanium Dioxide SDS MSDS Sheet, Material Safety Data Sheet. In the US, Canada, and most other jurisdictions, titanium dioxide is classified in Carcinogenicity – Category 2 under GHS. information: Titanium Dioxide On February 18, 2020, the European Union (EU) published the delegated regulation classifying certain powder titanium dioxide (TiO2) as a suspected carcinogen (Category 2) via inhalation under EU Regulation No 1272/2008 on classification, labelling, and packing (CLP) of substances and mixtures. The warning system of the Globally Harmonized System GHS is for the classification and labelling of substances / chemicals. Not applicable . Hazard classification under CLP may be harmonised, meaning that the regulatory authorities have determined the hazard of certain substances and specified these in Annex VI of the regulation. Titanium. Classification of the substance or mixture. Product name: Titanium ... GHS Label elements . 15468-32-3 5 - 15 Carc. 2, H351 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. For use at levels not to exceed 2.4 percent by weight of titanium dioxide. A transitional period of 18 months is given so that the ... be labelled with a GHS symbol (GHS08), a signal word (warning!) On the positive side, a classification of liquid mixtures with titanium dioxide (e.g. Titanium dioxide 25 35 13463-67-7 none none Synthetic resin 10 20 Confidential none Hazard statement Generic name weight % Registry No. Components CAS Number Weight % GHS‐US Classification Silica sand 14808‐60‐7 40‐60 Carcinogen (1A); STOT: RE (1) Styrene acrylic polymer 25586‐20‐3 7‐15 Eye Irritant (2B) Titanium dioxide 13463‐67‐7 1‐5 Carcinogen (2) Chemical Name CAS-No. 13463-67-7 20-30% Titanium dioxide 68187-64-4 0-10% Nepheline syenite 28064-14-4 20-25% Phenol, polymer with formaldehyde, glycidyl ether 4 FIRST AID MEASURES If affected, remove to fresh air. : 13463-67-7 Molecular Weight: 79.87 Chemical Formula: TiO2. Section 2 - Hazards Identification GHS Classification of the substance or mixture . CEPE, Titanium Dioxide Manufacturers Association (TDMA) and other industry organizations have criticized the conclusions of a study of Ti[O.sub.2], by scientific experts on ECHA's risk assessment committee (RAC) on which the CLP classification has been based. The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. 4 – First Aid Measures Ingestion (Swallowed): Aspiration Hazard. ... UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS) 15.1.4 EPA CPDat Classification. NTP Titanium dioxide (TiO 2, CAS 13463-67-7) now has two entries, one for nanoparticles and another excluding nanoparticles. Both entries have the classification “category 1, inhalation, repeated exposure, specific target organ toxicity,” Turley explained. Carcinogenicity: Titanium dioxide is listed by IARC as a category 2B carcinogen. - P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. This is in response to your letter of October 15, requesting information about the carcinogen status of titanium dioxide (TiO 2) relative to Occupational Safety and Health Administration (OSHA) standards. DO NOT induce vomiting. Contact: Heidi McAuliffe. GHS Classification of Mixture. regulation classifying certain powder titanium dioxide (TiO2) as a suspected carcinogen (Category 2) via inhalation under EU Regulation No 1272/2008 on classification, labelling, and packing (CLP) of substances and mixtures. Product identifier. In contrast, in the EU, it has not thus far been classified as a carcinogen. Titanium dioxide occurs naturally as the minerals rutile (tetragonalstructure), anatase (tetragonal structure), and brookite (orthorhombicstructure).Titanium dioxide may be prepared commercially by either thesulfate or chloride process. • 281 incidents US 1980-2005 • 269 incidents Japan 1952-1995 • 159 incidents UK 1979-1988 • 72 incidents China 1981-2011 Titanium. What is titanium dioxide? exposure to titanium dioxide. Blue = Health Red = ... titanium dioxide (anatase) Titanium oxide; (Titanium dioxide) 30 mg/m3 330 mg/m3 2,000 mg/m3 One of the substances mentioned in the amendment was titanium dioxide, a common ingredient in several cosmetic products. Other hazards Other hazards which do not result in classification : This product contains greater than 0.1% by weight titanium dioxide. This includes the classification of titanium dioxide (TiO2) for classification as carcinogenic category 2 by inhalation (Carc.2; H351i). GHS SDS PRECAUTIONARY STATEMENTS P363 Wash contaminated clothing before reuse.
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